Surface enhanced vibrational spectroscopic evidence for an alternative DNA-independent redox activation of endonuclease III.
نویسندگان
چکیده
Surface enhanced vibrational spectro-electrochemistry of endonuclease III provides direct evidence that the [4Fe-4S] cluster is responsible for the enzyme redox activity, and that this process is not exclusively DNA-mediated, as currently proposed. We report the first surface enhanced resonance Raman spectrum of a [4Fe-4S](2+) cluster containing enzyme.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 15 شماره
صفحات -
تاریخ انتشار 2015